TY - JOUR
T1 - A new insight into the catalytic decomposition of ethyl diazoacetate in the presence of meso-tetraarylporphyrin (=5,10,15,20-tetraaryl-21H,23H-porphine) complexes
AU - Gomes, Ana T.P.C.
AU - Leão, Raquel A.C.
AU - Alonso, Cristina M.A.
AU - Neves, Maria G.P.M.S.
AU - Faustino, Maria A.F.
AU - Tomé, Augusto C.
AU - Silva, Artur M.S.
AU - Pinheiro, Sergio
AU - De Souza, Maria Cecília B.V.
AU - Ferreira, Vítor F.
AU - Cavaleiro, José A.S.
PY - 2008/12
Y1 - 2008/12
N2 - The decomposition of ethyl diazoacetate by several catalysts in the presence of meso-tetraarylporphyrin complexes with different electronic features was evaluated. The distribution of the obtained products (chlorins, bacteriochlorins, isobacteriochlorins, and porphyrin derivatives resulting from C-H insertion and Büchner ring expansion) is dependent on the catalyst and on the electronic features of the meso-aryl groups.
AB - The decomposition of ethyl diazoacetate by several catalysts in the presence of meso-tetraarylporphyrin complexes with different electronic features was evaluated. The distribution of the obtained products (chlorins, bacteriochlorins, isobacteriochlorins, and porphyrin derivatives resulting from C-H insertion and Büchner ring expansion) is dependent on the catalyst and on the electronic features of the meso-aryl groups.
UR - https://www.scopus.com/pages/publications/58149090854
U2 - 10.1002/hlca.200890247
DO - 10.1002/hlca.200890247
M3 - Article
AN - SCOPUS:58149090854
SN - 0018-019X
VL - 91
SP - 2270
EP - 2283
JO - Helvetica Chimica Acta
JF - Helvetica Chimica Acta
IS - 12
ER -