A new insight into the catalytic decomposition of ethyl diazoacetate in the presence of meso-tetraarylporphyrin (=5,10,15,20-tetraaryl-21H,23H-porphine) complexes

Ana T.P.C. Gomes; Raquel A.C. Leão; Cristina M.A. Alonso; Maria G.P.M.S. Neves; Maria A.F. Faustino; Augusto C. Tomé; Artur M.S. Silva; Sergio Pinheiro; Maria Cecília B.V. De Souza; Vítor F. Ferreira; José A.S. Cavaleiro

doi:10.1002/hlca.200890247

A new insight into the catalytic decomposition of ethyl diazoacetate in the presence of meso-tetraarylporphyrin (=5,10,15,20-tetraaryl-21H,23H-porphine) complexes

Ana T.P.C. Gomes
, Raquel A.C. Leão
, Cristina M.A. Alonso
, Maria G.P.M.S. Neves
, Maria A.F. Faustino
, Augusto C. Tomé
, Artur M.S. Silva
, Sergio Pinheiro
, Maria Cecília B.V. De Souza
, Vítor F. Ferreira
, José A.S. Cavaleiro

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The decomposition of ethyl diazoacetate by several catalysts in the presence of meso-tetraarylporphyrin complexes with different electronic features was evaluated. The distribution of the obtained products (chlorins, bacteriochlorins, isobacteriochlorins, and porphyrin derivatives resulting from C-H insertion and Büchner ring expansion) is dependent on the catalyst and on the electronic features of the meso-aryl groups.

Original language	English
Pages (from-to)	2270-2283
Number of pages	14
Journal	Helvetica Chimica Acta
Volume	91
Issue number	12
DOIs	https://doi.org/10.1002/hlca.200890247
Publication status	Published - Dec 2008
Externally published	Yes

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10.1002/hlca.200890247

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Gomes, A. T. P. C., Leão, R. A. C., Alonso, C. M. A., Neves, M. G. P. M. S., Faustino, M. A. F., Tomé, A. C., Silva, A. M. S., Pinheiro, S., De Souza, M. C. B. V., Ferreira, V. F., & Cavaleiro, J. A. S. (2008). A new insight into the catalytic decomposition of ethyl diazoacetate in the presence of meso-tetraarylporphyrin (=5,10,15,20-tetraaryl-21H,23H-porphine) complexes. Helvetica Chimica Acta, 91(12), 2270-2283. https://doi.org/10.1002/hlca.200890247

@article{5146381c14344f61bddaf61febc3ece1,

title = "A new insight into the catalytic decomposition of ethyl diazoacetate in the presence of meso-tetraarylporphyrin (=5,10,15,20-tetraaryl-21H,23H-porphine) complexes",

abstract = "The decomposition of ethyl diazoacetate by several catalysts in the presence of meso-tetraarylporphyrin complexes with different electronic features was evaluated. The distribution of the obtained products (chlorins, bacteriochlorins, isobacteriochlorins, and porphyrin derivatives resulting from C-H insertion and B{\"u}chner ring expansion) is dependent on the catalyst and on the electronic features of the meso-aryl groups.",

author = "Gomes, \{Ana T.P.C.\} and Le{\~a}o, \{Raquel A.C.\} and Alonso, \{Cristina M.A.\} and Neves, \{Maria G.P.M.S.\} and Faustino, \{Maria A.F.\} and Tom{\'e}, \{Augusto C.\} and Silva, \{Artur M.S.\} and Sergio Pinheiro and \{De Souza\}, \{Maria Cec{\'i}lia B.V.\} and Ferreira, \{V{\'i}tor F.\} and Cavaleiro, \{Jos{\'e} A.S.\}",

year = "2008",

month = dec,

doi = "10.1002/hlca.200890247",

language = "English",

volume = "91",

pages = "2270--2283",

journal = "Helvetica Chimica Acta",

issn = "0018-019X",

publisher = "John Wiley and Sons Inc.",

number = "12",

}

Gomes, ATPC, Leão, RAC, Alonso, CMA, Neves, MGPMS, Faustino, MAF, Tomé, AC, Silva, AMS, Pinheiro, S, De Souza, MCBV, Ferreira, VF & Cavaleiro, JAS 2008, 'A new insight into the catalytic decomposition of ethyl diazoacetate in the presence of meso-tetraarylporphyrin (=5,10,15,20-tetraaryl-21H,23H-porphine) complexes', Helvetica Chimica Acta, vol. 91, no. 12, pp. 2270-2283. https://doi.org/10.1002/hlca.200890247

TY - JOUR

T1 - A new insight into the catalytic decomposition of ethyl diazoacetate in the presence of meso-tetraarylporphyrin (=5,10,15,20-tetraaryl-21H,23H-porphine) complexes

AU - Gomes, Ana T.P.C.

AU - Leão, Raquel A.C.

AU - Alonso, Cristina M.A.

AU - Neves, Maria G.P.M.S.

AU - Faustino, Maria A.F.

AU - Tomé, Augusto C.

AU - Silva, Artur M.S.

AU - Pinheiro, Sergio

AU - De Souza, Maria Cecília B.V.

AU - Ferreira, Vítor F.

AU - Cavaleiro, José A.S.

PY - 2008/12

Y1 - 2008/12

N2 - The decomposition of ethyl diazoacetate by several catalysts in the presence of meso-tetraarylporphyrin complexes with different electronic features was evaluated. The distribution of the obtained products (chlorins, bacteriochlorins, isobacteriochlorins, and porphyrin derivatives resulting from C-H insertion and Büchner ring expansion) is dependent on the catalyst and on the electronic features of the meso-aryl groups.

AB - The decomposition of ethyl diazoacetate by several catalysts in the presence of meso-tetraarylporphyrin complexes with different electronic features was evaluated. The distribution of the obtained products (chlorins, bacteriochlorins, isobacteriochlorins, and porphyrin derivatives resulting from C-H insertion and Büchner ring expansion) is dependent on the catalyst and on the electronic features of the meso-aryl groups.

UR - https://www.scopus.com/pages/publications/58149090854

U2 - 10.1002/hlca.200890247

DO - 10.1002/hlca.200890247

M3 - Article

AN - SCOPUS:58149090854

SN - 0018-019X

VL - 91

SP - 2270

EP - 2283

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 12

ER -

A new insight into the catalytic decomposition of ethyl diazoacetate in the presence of meso-tetraarylporphyrin (=5,10,15,20-tetraaryl-21H,23H-porphine) complexes

Abstract

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