TY - JOUR
T1 - Carbene transfer reactions catalysed by dyes of the metalloporphyrin group
AU - Simões, Mário M.Q.
AU - Gonzaga, Daniel T.G.
AU - Cardoso, Mariana F.C.
AU - Forezi, Luana Da S.M.
AU - Gomes, Ana T.P.C.
AU - Da Silva, Fernando De C.
AU - Ferreira, Vítor F.
AU - Neves, Maria G.P.M.S.
AU - Cavaleiro, José A.S.
N1 - Funding Information:
Thanks are due to the Portuguese Science and Technology Foundation (FCT), the European Union, QREN, FEDER and COMPETE for funding the research unit QOPNA (FCT UID/QUI/00062/2013). A.T.P.C.G. thanks FCT for her post-doctoral fellowship (SFRH/BPD/79521/2011). D.T.G.G. and M.F.C.C. thanks to FAPERJ for their post-doctoral fellowship. L.d.S.M.F. thanks to Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) for her post-doctoral fellowship. V.F.F. and F.d.C.d.S. thank Fundação de Amparo à Pesquisa do Estado do Rio de Janeiro (FAPERJ) and Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) for their research grants.
Funding Information:
Acknowledgments: Thanks are due to the Portuguese Science and Technology Foundation (FCT), the European Union, QREN, FEDER and COMPETE for funding the research unit QOPNA (FCT UID/QUI/00062/2013). A.T.P.C.G. thanks FCT for her post-doctoral fellowship (SFRH/BPD/79521/2011). D.T.G.G. and M.F.C.C. thanks to FAPERJ for their post-doctoral fellowship. L.d.S.M.F. thanks to Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) for her post-doctoral fellowship. V.F.F. and F.d.C.d.S. thank Fundação de Amparo à Pesquisa do Estado do Rio de Janeiro (FAPERJ) and Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) for their research grants.
Publisher Copyright:
© 2018 by the authors. Licensee MDPI, Basel, Switzerland.
PY - 2018
Y1 - 2018
N2 - Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chiral and achiral metalloporphyrins have been successfully explored as biomimetic catalysts for these carbene transfer reactions under both homogeneous and heterogeneous conditions. In this work the use of synthetic metalloporphyrins (MPorph, M = Fe, Ru, Os, Co, Rh, Ir, Sn) as homogeneous or heterogeneous catalysts for carbene transfer reactions in the last years is reviewed, almost exclusively focused on the literature since the year 2010, except when reference to older publications was deemed to be crucial.
AB - Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chiral and achiral metalloporphyrins have been successfully explored as biomimetic catalysts for these carbene transfer reactions under both homogeneous and heterogeneous conditions. In this work the use of synthetic metalloporphyrins (MPorph, M = Fe, Ru, Os, Co, Rh, Ir, Sn) as homogeneous or heterogeneous catalysts for carbene transfer reactions in the last years is reviewed, almost exclusively focused on the literature since the year 2010, except when reference to older publications was deemed to be crucial.
KW - Carbenes
KW - Cyclopropanation
KW - Cyclopropenation
KW - Metalloporphyrins
KW - Olefination
KW - Porphyrins
KW - X-H insertion
UR - http://www.scopus.com/inward/record.url?scp=85044848145&partnerID=8YFLogxK
U2 - 10.3390/molecules23040792
DO - 10.3390/molecules23040792
M3 - Review article
C2 - 29596367
AN - SCOPUS:85044848145
SN - 1420-3049
VL - 23
JO - Molecules
JF - Molecules
IS - 4
M1 - 792
ER -