Catalytic carbene insertion into an aminoporphyrin and formation of a new chiral supramolecular porphyrin system

Ana T.P.C. Gomes, Filipe A. Almeida Paz, Maria G.P.M.S. Neves*, Augusto C. Tomé, Artur M.S. Silva, Maria Cecília B.V. De Souza, Vítor F. Ferreira, José A.S. Cavaleiro

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

The catalytic insertion of ethyl diazoacetate into a porphyrin derivative bearing an NH2 substituent, in the presence of a Rh-based catalyst, was investigated. The X-ray analysis of one of the isolated products reveals the formation of a chiral supramolecular system.

Original languageEnglish
Pages (from-to)4741-4744
Number of pages4
JournalTetrahedron Letters
Volume52
Issue number37
DOIs
Publication statusPublished - 14 Sep 2011

Keywords

  • Carbene
  • Ethyl diazoacetate
  • Insertion reaction
  • Porphyrin

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