TY - JOUR
T1 - Synthesis of β-arylporphyrins and oligophenylenediporphyrins by the suzuki-miyaura reaction
AU - Cunha, Anna C.
AU - Gomes, Ana T.P.C.
AU - Ferreira, Vitor F.
AU - De Souza, Maria C.B.V.
AU - Neves, Maria G.P.M.S.
AU - Tomé, Augusto C.
AU - Silva, Artur M.S.
AU - Cavaleiro, José A.S.
PY - 2010/2
Y1 - 2010/2
N2 - Several β-aryl-substituted porphyrins were prepared in good yields by Suzuki-Miyaura cross-coupling of 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl) -5,10,15,20-tetraphenylporphinatozinc(II) with various aryl bromides. Additionally, syntheses of β,β-diporphyrins linked by biphenylene or quaterphenylene units were examined.
AB - Several β-aryl-substituted porphyrins were prepared in good yields by Suzuki-Miyaura cross-coupling of 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl) -5,10,15,20-tetraphenylporphinatozinc(II) with various aryl bromides. Additionally, syntheses of β,β-diporphyrins linked by biphenylene or quaterphenylene units were examined.
KW - Coupling
KW - Cross-coupling
KW - Oligophenylenes
KW - Porphyrins
KW - Suzuki-Miyaura reaction
UR - http://www.scopus.com/inward/record.url?scp=75149139382&partnerID=8YFLogxK
U2 - 10.1055/s-0029-1217114
DO - 10.1055/s-0029-1217114
M3 - Article
AN - SCOPUS:75149139382
SN - 0039-7881
SP - 510
EP - 514
JO - Synthesis
JF - Synthesis
IS - 3
M1 - Z19309SS
ER -