Synthesis of β-arylporphyrins and oligophenylenediporphyrins by the suzuki-miyaura reaction

Anna C. Cunha, Ana T.P.C. Gomes, Vitor F. Ferreira, Maria C.B.V. De Souza, Maria G.P.M.S. Neves, Augusto C. Tomé, Artur M.S. Silva, José A.S. Cavaleiro

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Several β-aryl-substituted porphyrins were prepared in good yields by Suzuki-Miyaura cross-coupling of 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl) -5,10,15,20-tetraphenylporphinatozinc(II) with various aryl bromides. Additionally, syntheses of β,β-diporphyrins linked by biphenylene or quaterphenylene units were examined.

Original languageEnglish
Article numberZ19309SS
Pages (from-to)510-514
Number of pages5
JournalSynthesis
Issue number3
DOIs
Publication statusPublished - 2010

Keywords

  • Coupling
  • Cross-coupling
  • Oligophenylenes
  • Porphyrins
  • Suzuki-Miyaura reaction

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